Known as “forever chemicals” due to their persistence in the environment, per- and polyfluoroalkyl substances (PFAS) are a broad class of fluorine-rich specialty chemicals. Thousands of different PFAS are registered for use in consumer, commercial and industrial applications. Increased use has led to the widespread presence of PFAS in our natural environment, including San Francisco Bay. PFAS are a high priority for action at federal, state, and local levels due to the well-documented toxic properties of key members of this class of contaminants.
Stormwater agencies in the San Francisco Bay Area are identifying watershed areas that are polluted with PCBs in order to prioritize management efforts to reduce impairment in the Bay caused by PCBs carried in stormwater. Water sampling during storms has been used to characterize PCB concentrations but management prioritization based on the comparison of concentrations between watersheds is made difficult due to variations in flow and sediment erosion between storms and in relation to varying land use. In addition, identifying PCB source areas within priority watersheds has proven complex and costly. To address these challenges, the San Francisco Bay Regional Monitoring Program (RMP) has developed two new interpretive methods based on storm-event PCB yields (PCBs mass per unit area per unit time) and fingerprints of Aroclors (commercial PCB mixtures) that make existing data more useful for decision-making.
The objectives of this study were to:
Apply the yield method to the regional stormwater dataset and provide new rankings,
Estimate the presence of Aroclors in samples where congener data are available
Evaluate data weaknesses and recommend watersheds to resample, and
Classify watersheds into high, medium, and low categories for potential management.
Conceptual models developed for selected San Francisco Bay margin areas (referred to as priority margin units, or PMUs) have identified shiner surfperch as a crucial indicator of PCB impairment, due to their explicit inclusion as an indicator species in the PCBs TMDL, importance as a popular sport fish species, tendency to accumulate high PCB concentrations, site fidelity, and other factors. The conceptual models recommend periodic monitoring of shiner surfperch to track trends in the PMUs, and as the ultimate indicator of progress in reduction of impairment. The objectives of this study were to 1) establish baselines for long-term monitoring of PCB concentrations in shiner surfperch in four PMUs, and 2) understand local spatial variation in shiner PCB concentrations to support optimization of the long-term sampling design. This study also provided valuable information on the presence of shiner surfperch and other species in the PMUs.
This report details activities associated with the Regional Monitoring Program North Bay Selenium Study in 2020 and 2021. The study was designed to monitor two sites for selenium (Se) in water and clam tissue six times annually between June and February. Due to the COVID pandemic, however, four sample collection events were completed. This report outlines the sampling activities, personnel, and site locations monitored for the project.
Urban-wildland interfaces in the western US are increasingly threatened by the growing number and intensity of wildfires, potentially changing the type of contaminants released into the landscape as more urban structures are burned. In October 2017, the Tubbs, Nuns, and Atlas wildfires devastated communities in Northern California (Figure 1), burning over 8,500 buildings and 210,000 acres of land in the span of 24 days (California Department of Forestry and Fire Protection 2017). Together, these wildfires were the most destructive and costliest fires in the history of California at that time (California Department of Forestry and Fire Protection 2019).
Post-wildfire monitoring efforts in impacted watersheds typically focus on a few well-established water quality and chemistry concerns (McKee et al. 2018). Few studies go beyond these limited targeted analyses and attempt to identify the multitude of other fire-related compounds that are released from or form as the result of combustion of residential, commercial, and industrial structures in urban-wildland interfaces. Some of these unidentified compounds may be toxic to aquatic ecosystems or human health, and may pose risks to wildlife or in water bodies that act as drinking water supplies to nearby communities.
Recent studies by the San Francisco Estuary Institute (SFEI) and the Regional Monitoring Program (RMP) have pinpointed chemical and microplastic contamination from tires as a rising concern in the Bay. Tire ingredients of interest include zinc, which has many documented adverse health effects in wildlife, and 6PPD, a preservative