Introduction
Welcome to the first issue of the San Francisco Bay Mercury
News!
This electronic newsletter will be issued bi-annually and is
intended to be a compilation of mercury research activities currently
underway in the Bay Area. Each researcher has provided a summary
paragraph regarding the purpose of their research and recently
accomplished milestones. Contact information follows each project
summary. The newsletter is distributed by the San Francisco Estuary
Institute as part of the Regional Monitoring Program. A table
of contents follows this introduction. To move directly to a description
of a project listed in the table of contents, click on the title.
Alternatively, you can browse through the entire newsletter
by scrolling down. The next issue of the SF Bay Mercury News will
be released the first week of February 2005.
We welcome contributions to the newsletter and are actively
seeking new contributors. If you have a summary for the
newsletter or questions or comments regarding the content of this
newsletter please e-mail or call Meg Sedlak at SFEI (meg@sfei.org
or tel. (510) 746-7345) .
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In this issue
On-going Projects
1. Evaluation of Hg Transformations
and Trophic Transfer in the SF Bay/Delta: Identifying Critical
Processes for the Ecosystem Restoration Program. An investigation
by USGS, University of Maryland and SUNY-Stony Brook.
2. A Pilot Program for Monitoring, Stakeholder
Involvement, and Risk Communication Relating to Hg in Fish in
the Bay-Delta Watershed (CBDA Fish Hg Pilot Program). Project
led by SFEI, UC Davis, Moss Landing Marine Lab, Cal DHS, and Cal
OEHHA.
3. Concentration and Production of Methylmercury
in Wetlands in the Bay. Research project by US Army Corps of Engineers.
4. Description of UCSC’s Hg Studies
in the San Francisco Bay Area and Recent Publications.
5. Wetland Design and Management Options
for Control of Hg in SF Bay. LFR Levine-Fricke and WIGS Laboratory
at UCSC.
6. Mercury and Methylmercury Processes
in North San Francisco Bay Tidal Wetland Ecosystems. Project led
by SFEI.
7. Status Report on Guadalupe River Watershed
Mercury TMDL.
8. UCDavis Study of Bioavailability of
Mercury and Production of Methyl Mercury in Stege Marsh and Walker
Creek Estuary.
9. Annual Monitoring for Hg and Other Contaminant
Concentrations and Loads in the Guadalupe River Watershed, San
Jose, CA. A study by SFEI.
10.Montezuma Wetlands
Project. Comprehensive Monitoring Program (including mercury in
water, sediment, and tissues) at the Site and at Suisun Marsh
Reference Sites
New Reports/Recent Academic Theses
1. Legacy Contaminants in the Bay. Forthcoming
report from BCDC.
2. The San Francisco Bay Regional Water
Quality Control Board to release New Fish Contaminant Study in
October 2004
3. Mercury Research of Potential Relevance
to San Francisco Bay. UC-Berkeley
Upcoming Hg Conferences/Workshops
1. San Francisco Bay Wetland Mercury
Research Coordination Meeting, February 23, 2005
2. Eighth International Conference on
Mercury as a Global Pollutant, August 6-11, 2006
Project Summaries
1. Evaluation of Mercury
Transformations and Trophic Transfer in the San Francisco Bay/Delta:
Identifying Critical Processes For The Ecosystem Restoration Program
In September 2003, researchers from the USGS, the
University of Maryland and the State University of New York (Stony
Brook) began a three-year project funded by CALFED to explore
processes controlling the mercury transformations and bioaccumulation
in the San Francisco Bay Delta. The overall goal of this project
is to better understand processes that underlie previously reported
observations that the mercury contamination of biota is low in
the central Delta and high in the rivers flowing into the Delta.
The study is designed to test whether this trend is based on spatial
differences in the production and/or degradation of methylmercury,
methylmercury transfer efficiencies into the base of the food
web, food web structure, or some combination of these potential
factors. The two primary study regions being compared and contrasted
are Frank’s Tract in the central Delta and the Cosumnes
River. Within these regions the investigation includes three primary
sub-habitats: emergent marsh, areas of dense submerged vegetation
(i.e. Brazilian waterweed, Egeria densa), and non-vegetated
open water. This research is ongoing with two field trips having
been conducted to date (December ’03 and June ’04)
and more fieldwork to be conducted throughout 2005. In year three
the study focus will shift to mercury transformation and bioaccumulation
processes associated with the Cosumnes River floodplain.
Contact Information: For more
information on this project, please contact the primary investigators
listed below.
Mercury transformations in sediment and water;
Dr. Mark Marvin-DiPasquale (
mmarvin@usgs.gov )
Pathways of mercury accumulation in food webs;
Dr. Robin Stewart ( arstewar@usgs.gov
).
Mercury concentrations in water sediment and biota;
Dr. Robert Mason ( mason@cbl.umces.edu
)
Kinetics of mercury uptake into the base of the
food web; Drs. Paul Pickhardt (
ppickhardt@notes.cc.sunysb.edu ) and Nicholas Fisher (
nicholas.fisher@sunysb.edu ),
2. A Pilot Program for Monitoring,
Stakeholder Involvement, and Risk Communication Relating to Mercury
in Fish in the Bay-Delta Watershed (CBDA Fish Mercury Pilot Program)
In August the Board of Directors for the California
Bay-Delta Authority approved funding of a $4.5 million proposal
to monitor mercury in fish in the Bay-Delta watershed, establish
an organizational structure to allow stakeholder input on the
monitoring, and conduct risk assessment and risk communication
activities to raise public awareness about fish contamination
issues with the goal of reducing human exposure to methylmercury
in the watershed. Partners in this project include SFEI,
UC Davis, Moss Landing Marine Lab, the California Department of
Health Services, and the California Office of Environmental Health
Hazard Assessment. This project will include monitoring
of 1) sport fish to characterize human exposure and spatial patterns
and 2) small fish as an indicator of temporal and spatial patterns
and exposure of piscivorous wildlife. The sampling will
include trend monitoring sites, screening of areas in the watershed
that have not recently been sampled, and monitoring of restoration
projects. Availability of the funds is anticipated within
the next few months. As soon as funds are available a Steering
Committee will be formed to guide the design of the monitoring
program. Sampling will begin in summer of 2005.
Contact Information: Stakeholders interested
in participating in this study should contact:
Rainer Hoenicke at SFEI ( rainer@sfei.org
).
Other contacts: Sport fish sampling: Jay Davis, SFEI
( jay@sfei.org )
Small fish sampling: Darell Slotton, UC Davis (
dgslotton@ucdavis.edu )
Public involvement and communication: Alyce Ujihara, DHS (
aujihara@dhs.ca.gov )
Advisory development: Bob Brodberg, OEHHA (
rbrodber@oehha.ca.gov )
3 Concentration and Production of
Methylmercury in Wetlands in the Bay –
U.S. Army Corps of Engineers
Restoration of wetlands around San Francisco Bay requires
filling subsided areas to a level that will support aquatic macrophytes
that will in turn continue to trap sediments transported
by rivers. Materials being transported from Corps of Engineers
dredging operations in the Bay can be used for this purpose. This
use would save the Government the cost of finding and transporting
other material to the restoration sites and the cost of transporting
the dredge material to a remote disposal site, a potential win
- win situation. The Corps of Engineers San Francisco District is
working with the San Francisco Bay Conservation and Development
Commission, the California State Coastal Conservancy, and other
stakeholders to integrate this beneficial use of dredged material
into its Long Term Management Strategy. As the environmental research
and development arm of the Corps of Engineers, the Engineer Research
and Development Centers' Environmental laboratory has been conducting
field and laboratory studies designed to address technical questions
framed at the CALFED Stakeholders meeting at Moss Point Marine
Laboratory, 8-9 October in 2002.
These include:
- What are the present levels of methylmercury (MeHg)
in SF Bay wetlands with respect to biota, sub-habitats, and
location within the Bay?
- What are the rates of MeHg production?
- What factors control production? Can these be managed?
- Are some wetlands larger mercury exporters than others?
- Can we model/predict the effects of wetland restoration on
MeHg production and export?
The majority of our work to date has centered on the Hamilton
Army Airfield and China Camp (reference) sites on San Pablo Bay.
This year we expand our work to include the Sonoma Baylands and
other sites.
Contact Information:
Dr. Herb Frederickson (
Herbert.L.Frederickson@erdc.usace.army.mil )
4. Mercury Studies in the San
Francisco Bay Area. University of California, Santa Cruz
The WIGS laboratory at UCSC is involved in several projects
on the biogeochemical cycling of mercury in the San Francisco
Bay area, with funding provided by the Regional Monitoring Program
(RMP), University of California Toxic Substances Research &
Teaching Program (UC TSR&TP), National Science Foundation
(NSF), and a National Institute of Health (NIH) superfund grant
to Dr. Jim Hunt at UC Berkeley. The RMP studies focus on temporal
and spatial variations in the concentrations and speciation of
mercury in Bay waters and on the particulate flux of mercury into
the Bay during high freshwater discharges at Mallard Island. The
latter study is being directed by Lester McKee of SFEI. In addition,
we are working with David Schoellhammer of the USGS on two projects
that are based on RMP data: (1) modeling particulate mercury cycling
in the Bay and (2) its export from the system. Two of the UC TSR&TP
studies are investigating (1) the effect of algal blooms on mercury
concentration, speciation and bioavailability in the South Bay
and (2) the atmospheric evasion of mercury from the Bay. These
are being conducted in collaboration with Jim Cloern and Sam Luoma
of the USGS. The other UC TSR&TP studies, that are just being
initiated, are looking at the bioaccumulation of mercury in benthic
invertebrates (Fionna Morris), atmospheric mercury fluxes (Melanie
Gault), and sublethal mercury toxicity in fish (Mary Langsner).
The NSF study, which is a graduate fellowship for Frank Black,
is investigating the factors influencing the bioavailability of
organic mercury species in fresh water systems discharging into
the Bay. It is an extension of previous studies by David Sedlak’s
group at UC Berkeley, and he is contributing to the project’s
oversight as a member of Frank’s graduate committee.
The NIH study on the mercury concentration of petroleum products
and their contribution to atmospheric mercury fluxes in the Bay
area has been accepted for publication in Atmospheric Environment
(Conaway et al., ms in press). The article includes Rob Mason
from Chesapeake Biological Laboratory as a co-author and acknowledges
the contributions of Geoff Brosseau of the Bay Area Stormwater
Management Agencies Association and Fred Schmidt of the California
Air Resources Control Board. Another article on the geochronology
of mercury fluxes in the South Bay, which was conducted in collaboration
with Elizabeth Watson at UC Berkeley, is being published in Marine
Chemistry (Conaway et al., 2004) – the electronic version
already out. That study was supported by the San Francisco Regional
Water Quality Control Board and supervised by Richard Looker.
Another article on mercury speciation in Bay waters, written in
collaboration with Rob Mason at Chesapeake Biological Laboratory,
was published in Marine Chemistry within the past twelve
months (Conaway et al., 2003), as were two related articles in
(1) Environmental Science & Technology that contrasted
the relative wealth of information that has been reported on metals
in San Francisco Bay compared to other estuaries (Sañudo-Wilhelmy
et al., 2004) and (2) in Estuarine, Coastal and Shelf Science
that compared cobalt cycles in San Francisco Bay and the Hudson
River Estuary (Tovar-Sanchez et al., 2004). The latter two articles
were written in collaboration with a previous graduate student
participant in the RMP, Sergio Sañudo-Wilhelmy, and his
colleagues at Stony Brook University. In addition, J.R. Flanders
(2004) just completed his MS in Environmental Toxicology, with
substantial input from Cindy Gilmour of the Smithsonian Institution,
with a thesis on the effect of organic and inorganic ligands on
the bioavailability, uptake and methylation of inorganic mercury
by sulfate-reducing bacteria.
Publications:
Conaway, C., S. Squire, R.P. Mason, and A.R. Flegal. 2003. Mercury
speciation in the San Francisco Bay estuary. Marine Chemistry
80: 199-225.
Conaway, C. H., E. Watson, J.R. Flanders and A.R. Flegal. 2004.
Assessing historic mercury concentrations in sediments, San Francisco
Bay estuary. Marine Chemistry (in press).
Conaway, C.H. R.P. Mason, D.J. Steding, R. Mason and A.R. Flegal.
2004. Estimate of mercury emission from gasoline and diesel fuel
consumption, San Francisco Bay area, California. Atmospheric
Environment (in press).
Flanders, J.R. 2004. The Effect of Organic and Inorganic
Ligands on the Biioavailability, Uptake, and Methylation of Inroganic
Mercury by Desulkfobulbos propionicus sp. MS Thesis,
Environmental Toxicology, University of California, Santa Cruz
pp.83.
Sañudo-Wilhelmy, S.A., A. Tovar-Sanchez, N.S. Fisher
and A.R. Flegal. 2004. Examining toxic metals in U.S. estuaries.
Environmental Science and Technology: 34A-38A.
Tovar-Sanchez, A., S.A. Sañudo-Wilhelmy, and A.R. Flegal.
2004. Temporal and spatial variations in the biogeochemical cycle
of cobalt in two estuaries: Hudson River and San Francisco Bay.
Estuaries, Coastal and Shelf Science (in press).
Contact Information:
Russ Flegal Flegal@etox.ucsc.edu
5. Wetland Design and Management
Options for Control of Mercury in SF Bay. LFR Levine-Fricke and
WIGS Laboratory at UCSC
LFR Levine-Fricke, WIGS Laboratory, and several other collaborating
organizations have received authorization to identify management
options that could reduce methylmercury production in tidal wetlands
of San Francisco Bay. The project will estimate methylmercury
production in wetland habitats, identify wetland management and
design options to inhibit production of methylmercury, and develop
monitoring protocols and tools for calculating load reductions.
The project has been tentatively approved but a contract is not
yet in place. It is anticipated that work will commence
in early 2005.
Contact information:
Phil Lebednik Phillip.Lebednik@lfr.com
6. Mercury
and Methylmercury Processes in North San Francisco Bay Tidal Wetland
Ecosystems
In December 2003, the California Bay-Delta Authority
(CBDA) Board of Directors approved funding of a $1.6 million proposal
to study mercury and methymercury processes in wetlands of the
Petaluma River and San Pablo Bay. Partners in this project include
SFEI, USGS Menlo Park, USGS Biological Resources Division, USGS
Wisconsin, and Avocet Associates. A primary interest of this project
is to examine processes that lead to mercury exposure and accumulation
by several species of threatened or endangered wetland birds,
including the California clapper rail. This project will examine
Hg and methylmercury (MeHg) concentrations in the sediments, water
and biota of five tidal marshes along a salinity gradient up Petaluma
River. Influences of seasonal and interannual variation in environmental
parameters on Hg geochemistry and bioaccumulation will also be
examined. Physiographic differences among marshes of different
ages to be studied are also expected to impact Hg geochemistry.
Relationships found previously in other estuarine ecosystems will
be sought, and changes with marsh progression will be examined
to project likely long-term outcomes of restoration projects.
This knowledge is needed for deciding where and how to restore
selected wetlands and to anticipate possible impacts of projects.
For restoration projects that proceed, additional studies can
then be conducted to confirm projected changes and further refine
understanding of Hg transformation and bioaccumulation processes
in an adaptive management process. The project is currently in
contracting with CBDA, with planning and scoping work anticipated
starting in November 2004. Sampling will begin in winter
of 2004-5.
Contact information:
Donald Yee, SFEI donald@sfei.org
7. Status Report of Guadalupe
River Watershed Mercury TMDL
Progress February - May 2004
Completed an extensive wet season sampling effort of stormwater
and sediment samples. Draft Data Collection Report, Part 1: Wet
Season Sampling, available on CD from Dave Drury (
ddrury@valleywater.org ). Work performed by Tetra Tech and
funded by the Santa Clara Valley Water District.
Progress May - September 2004
Completed extensive fish sampling in creeks, the River, Lake Almaden
and four reservoirs. Completed methylmercury production sampling
in two reservoirs. Completed phyto- and zooplankton sampling in
Lake Almaden and four reservoirs. Data to be reported in the forthcoming
Draft Data Collection Report, Part 2: Dry Season Sampling. Work
and report performed by Tetra Tech, funded by the Santa Clara
Valley Water District, with in-kind services from USGS and USEPA.
Work to be Conducted Oct - December 2004
Tetra Tech will commence writing the Final Conceptual Model with
funding from USEPA under contract to the Water Board.
Contact Information:
Dave Drury at the Santa Clara Valley Water District (
ddrury@valleywater.org ) or
Carrie Austin at the Regional Water Quality Control Board (
cma@rb2.swrcb.ca.gov )
8. UC-Davis Study of Bioavailability
of Mercury and Production of Methyl Mercury in Stege Marsh and
Walker Creek Estuary
The original goal of our PEEIR-supported study was to
determine whether there were site-to site differences at Walker
Creek Estuary (Tomales Bay, CA) in bioavailability of inorganic
mercury or in production of methylmercury by sediment bacteria.
At this site, which experiences Hg-contamination from the Gambonini
Mine, sediment Hg levels were found to be extremely heterogeneous
even on a small scale, and this made identification of high and
low-Hg sites problematic. Thus, we switched to a focus on the
[Hg] in leg muscle of the “lined shore crab” as our
survey tool and also included: (1) Tom’s Point Estuary as
a putative non-impacted control site, 1.5 km removed from Walker
Creek, and (2) Stege Marsh, which is impacted by diverse heavy
metal and xenobiotic contaminants and also by the normal Hg-load
from San Francisco Bay. The concentration of Hg in crab muscle
emerged as an intriguing indicator/ integrator of Hg-bioavailability
within a given estuary. We found very different tendencies for
trophic magnification (within individual lined shore crabs of
different sizes) depending on the estuary selected. Stege Marsh
crabs showed moderate Hg levels (200 ppb; wet weight) and no tendency
toward biomagnification in larger individuals, while large crabs
from Walker Creek contained in excess of 1000 ppb Hg, roughly
five times the concentration found in small individuals there.
Elevated concentrations were also detected in Tom’s Point
crabs, which suggests that the impact of the mine extends beyond
Walker Creek Estuary. Low-Hg crabs collected at Bodega Marine
Lab Reserve, “outplanted” to these diverse estuarine
sites, and fed local food sources showed similar tendencies to
bioaccumulate Hg regardless of the site to which they were transferred.
Because this finding is at odds with our survey data, we are investigating
trophic levels of the various crabs via 15N analyses. We are also
investigating how far up and down Tomales Bay the impact of the
Gambonini Mine can be detected using indicator crabs.
Contact Information:
Doug Nelson at UC-Davis
dcnelson@ucdavis.edu
9. Annual monitoring for Hg and
other contaminant concentrations and loads in the Guadalupe River
watershed, San Jose, CA.
With funding from the Clean Estuary Partnership (CEP), the San
Francisco Estuary Institute (SFEI) began a three-year study in
June 2002 to determine the concentrations and loads of suspended
sediments, mercury, trace metals, polychlorinated biphenyls (PCBs),
and organochlorine pesticides (DDT, chlordane and dieldrin) in
the Guadalupe River, San Jose. Water bodies adjacent to and downstream
from the historic New Almaden Mining District, once the largest
producer of mercury in North America are contaminated with mercury.
Urban areas of the lower portion of the watershed have lower levels
of mercury contamination and are also contaminated with PCBs.
With funding provided by the Regional Monitoring Program for Trace
Substances (RMP) and the CEP, the study continued during WY 2004,
and SFEI has just secured funding from the RMP, the United State
Army Corps of Engineers and Santa Clara Valley Water District
for WY 2005. The new United States Geological Survey (USGS) flow
gauge at Hwy 101 provides an ideal sampling location – close
to the Bay and downstream from most of the urban area, safe from
vandalism, and well-lit by street lamps. During the first year
of the study, 26 samples for mercury analysis were collected using
Clean Hands techniques. Concentrations of total mercury varied
from 0.2-18.7 µg/L. A mercury load of 116 kg was calculated
using sediment data collected on a 15-minute basis using a DTS-12
turbidity probe and flow data provided by the USGS. During the
second year of study, rainfall and floods were smaller. Concentrations
of total mercury varied from the detection limit to 1,419 µg/L
(n=40). Analysis and reporting for the second year of data will
be completed by the end of 2004. This study has helped to affirm
the importance of loads of trace substances in small local tributaries
of the Bay relative to the much larger Sacramento/ San Joaquin
River system. The continuation of this study is important for
helping storm water agencies and regulatory authorities to make
difficult management decisions about how to reduce mercury contamination
in the Bay. The data also provide a means for determining trends
and the success of management actions.
Contact Information:
Guadalupe River study: Lester McKee (SFEI)
lester@sfei.org
Guadalupe River Hg impairment: Carrie Austin (SFRWQCB)
cma@rb2.swrcb.ca.gov
San Francisco Bay Hg impairment: Richard Looker (SFRWQCB)
rel@rb2.swrcb.ca.gov
10. Montezuma Wetlands Project.
Comprehensive Monitoring Program (including mercury in water,
sediment, and tissues) at the Site and at Suisun Marsh Reference
Sites
The Montezuma Wetlands Project will restore over 1,800
acres of historical tidal wetlands in the brackish Suisun Marsh
by raising subsided site elevations using approximately 17 million
cubic yards of sediment dredged from SF Bay-Delta harbors and
channels. The project site comprises about 2,500 acres at the
eastern edge of Suisun Marsh. The project will restore a variety
of habitats, including tidal wetlands, seasonal wetlands, and
vernal pools; aiding in the recovery of important threatened and
endangered fish, birds, mammals, invertebrates, and plants. Restoration
efforts will be conducted in four hydrologically discrete phases
so that impacts to existing biological resources at the site will
be minimized and wetland habitat values maximized through adaptive
management.
Construction of Phase I wetlands and the necessary infrastructure
for offloading and placing sediment was started in 2002, and to-date
more than 500,000 cubic yards (cy) of sediment have been placed
at the site. Another 1.3 million cy of sediment will be placed
during the fall 2004 through summer 2005. Restoration of all four
phases is expected to take 15 to20 years, depending on the availability
of dredged sediment. The monitoring efforts will continue for
at least 10 years after completion of each project phase.
The Project’s monitoring program includes the measurement
of numerous chemicals of concern (COCs; e.g., inorganics, PAHs,
pesticides, PCBs, dioxins, and radiation) in sediment, water,
and tissue. Monitoring is conducted on-site during sediment placement
activities and will continue for at least 10 years after restoration
is completed. Additionally, the project conducts monitoring at
selected Suisun Marsh reference sites (e.g., Rush Ranch, Hill
Slough) to assess background levels of COCs in local tidal marshes.
Mercury is just one element in the monitoring program, but because
of its bioaccumulative characteristics it is a major component
of tissue monitoring in invertebrates and fish. Initial reports
on reference site monitoring were completed in 2003 and 2004,
and the Project’s first on-site monitoring reports are expected
to be released in Fall 2004. A Technical Review Team (TRT), administered
by SFEI, reviews and comments on Montezuma’s reports and
adaptive management strategies.
Contact Information:
For site information, contact:
Doug Lipton, Montezuma’s Project Manager, Lipton Environmental
Group ( docterre@sonic.net
)
For information on the TRT, contact Josh Collins at SFEI (
josh@sfei.org )
Report Summaries
1. Legacy Contaminants in the Bay
BCDC is a state permitting and planning agency that is guided
by its law and its policies in the San Francisco Bay Plan
(Bay Plan) when reviewing and authorizing projects in the SF Bay
and shoreline to ensure resources are protected. The Bay Plan
includes findings and policies on water quality protection. These
policies were last updated in June 2003 to address nonpoint source
pollution in the Bay. As a continuation of the water quality policy
update, BCDC staff is now reviewing issues surrounding legacy
contaminants in the Bay. BCDC staff is currently preparing a draft
background report, entitled Mercury, PCBs, and other Legacy
Contaminants in San Francisco Bay, which will summarize and
present available scientific and technical information on legacy
contaminants in the Bay, including a large chapter on mercury.
The mercury chapter will include, as available, the following
information: (1) a description of the problem and impacts on human
health and wildlife, and primary issues regarding the ecological
restoration and management of tidal wetlands; (2) mercury trends;
(3) historical uses and practices; (4) fate and transport; (5)
sources and loads; (6) strategies; and (7) gaps and needs. This
draft report is intended to be the basis for any proposed revisions
to existing Bay Plan water quality findings and policies, and
for any other possible recommendations to the Commission.
Contact Information:
Lisa Sniderman, Nonpoint Source Program Coordinator at
BCDC ( lisab@bcdc.ca.gov
).
2. The San
Francisco Bay Regional Water Quality Control
Boards to release New Fish Contaminant Study in October 2004
As part of the California Surface Water Ambient Monitoring
Program (SWAMP), the State Water Resources Control Board and Regional
Water Quality Control Boards have undertaken a series of studies
to evaluate the condition of California's water resources. In
October 2004, the San Francisco Bay Regional Water Quality Control
Board will be issuing a SWAMP report describing studies measuring
contaminant levels in fish tissue in reservoirs and coastal areas
in the San Francisco Bay region. In this study, edible fish were
collected and their tissues analyzed to determine the concentrations
of contaminants (e.g., mercury, PCBs, and pesticides) which may
affect human health. These and other data are being used by staff
from the State Office of Environmental Health Hazard Assessment
(OEHHA) to determine whether and what type of advisories should
be issued related to the consumption of fish from the surveyed
reservoirs and coastal waters.
Contact information:
For additional information, please contact
Karen Taberski at the Regional Water Quality Control Board (
KMT@rb.2.swrcb.ca.gov ).
3. Mercury
Research of Potential Relevance to San Francisco Bay. University
of California, Berkeley
Two recently completed Ph.D. dissertations from students
in the Department of Civil and Environmental Engineering at UC
Berkeley may be of interest to researchers studying mercury in
San Francisco Bay.
The dissertation of Anna Mehrotra, titled, “Using Iron
Amendments to Reduce Mercury Methylation in Engineered Wetland
Sediments” demonstrated that the addition of ferrous chloride
to wetland sediments reduces the rate of mercury methylation by
up to 95%. The addition of iron to the sediments reduces
in the concentration of bisulfide (HS -) in the sediments, which
in turn lowers the concentration of dissolved bioavailable Hg(II)
species, such as Hg(HS) 2 0. The reduction in concentrations
of these species slows the net rate of mercury methylation.
The dissertation includes experiments conducted with pure cultures
of the mercury-methylating organism Desulfobulbus propionicus
(1pr3) in the absence of sediment, experiments with mixed microbial
cultures in sediments from five locations in San Francisco Bay
and experiments in laboratory microcosms designed to simulate
tidal wetlands. Results of the pure culture experiments
were published in Environmental Science & Technology
in 2003 (Mehrotra et al., 2003) and other publications are forthcoming.
Dr. Mehrotra was supervised by Alex Horne and David Sedlak.
The dissertation of Helen Hsu, titled, “Complexation of
Mercury(II) by Reduced Sulfur-Containing Ligands in Municipal
Wastewater Effluent and Oxic Surface Waters” examined the
speciation of Hg(II) in wastewater effluent and surface waters.
Through the use of a new, competitive ligand exchange/chelating
resin technique, Dr. Hsu demonstrated that wastewater effluent
contains relatively high concentrations of a ligand that is capable
of forming extremely strong complexes with Hg(II). Samples
collected from eutrophic lakes and downstream of the New Almaden
mine contained weaker Hg(II)-complexing ligands. Species
that may explain the strong ligands in wastewater effluent include
sulfide, polysulfide and filterable clusters or polymers that
contain ZnS and FeS. Measurements of Hg(II) speciation in
wastewater effluent and surface water samples from San Francisco
Bay were published in Environmental Science & Technology
in 2003 (Hsu and Sedlak, 2003). Other publications are forthcoming.
Dr. Hsu was supervised by David Sedlak.
Mehrotra A.S., Horne A.J. and Sedlak D.L. (2003) Inhibition
of net mercury methylation by iron in Desulfobulbus propionicus
cultures: implications for engineered wetlands. Environ. Sci.
Technol. 37, 3018-3023.
Hsu H. and Sedlak D.L. (2003) Strong Hg(II) complexation in
municipal wastewater effluent and surface waters. Environ.
Sci. Technol. 37, 2743-2749.
For reprints of these papers or the two Ph.D. theses, please
contact David Sedlak (Sedlak@ce.berkeley.edu)
Upcoming Hg Workshops/Conferences
1. San FranciscoBay
Wetland Mercury Research Coordination Meeting, February 23, 2005.
This annual workshop brings together researchers, regulators,
and stakeholders to discuss recent developments in the area of
wetland mercury research. The purpose of the meetings is
to facilitate the exchange of mercury information among these
groups to foster collaboration. Last year’s meeting
was quite well attended and productive. Information
about this workshop will be available closer to the date of the
workshop.
2. Eighth International Conference
on Mercury as a Global Pollutant
The International Conference on Mercury as a Global Pollutant
has become the preeminent international forum for formal presentation
and discussion of scientific advances concerning environmental
mercury pollution. The depth, breadth, and pace of scientific
discovery on the sources, environmental transport and fate, biogeochemical
cycling, and adverse effects of mercury have increased enormously
since the inaugural conference was convened in Sweden in 1990.
In view of proposed U.S. and international actions on mercury
emissions, the 2006 conference will present a timely opportunity
to assimilate, synthesize, and disseminate scientific knowledge
and technical information in a form useful to policy discussions
involving mercury in the environment.
The 8th International Conference on Mercury as a Global Pollutant
will be convened in Madison, Wisconsin (USA), at the Monona Terrace
Community and Convention Center, an extraordinary conference facility
designed by the famed architect Frank Lloyd Wright. You are invited
to participate in this global mercury conference, which will again
feature scientific advances in mercury research, with an expanded
scope to include socioeconomic issues and public policy.
For more information regarding this conference, please see our
web site www.mercury2006.org.